MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols
Short Product Description
MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols is a high-surface-area activated manganese dioxide designed for selective oxidation in organic synthesis. The material typically provides 85–92% MnO₂ purity with strong surface reactivity. It is widely used in laboratories and fine chemical production for converting allylic and benzylic alcohols into the corresponding aldehydes or ketones.

Technical Specifications
| Parameter | Typical Value |
|---|---|
| MnO₂ Purity | 85–92% |
| Particle Size | 5–30 µm |
| Surface Area | 60–120 m²/g |
| Moisture | ≤1.0% |
| Bulk Density | 0.45–0.65 g/cm³ |
| Crystal Phase | Predominantly γ-MnO₂ |
Key Features
• High oxidation activity – large surface area improves reaction efficiency in alcohol oxidation reactions.
• Selective oxidation performance – efficiently converts allylic and benzylic alcohols to aldehydes or ketones without significant over-oxidation.
• Stable purity consistency – controlled manufacturing ensures reliable MnO₂ purity across production batches.
• Enhanced surface reactivity – porous structure provides strong contact with organic substrates.
• Easy filtration and handling – optimized particle size distribution simplifies post-reaction separation.
• Designed for organic synthesis – MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols provides reliable catalytic behavior in laboratory and industrial reactions.
Applications
• Selective oxidation of allylic alcohols – active MnO₂ efficiently converts allylic alcohols into corresponding aldehydes.
• Benzylic alcohol oxidation – suitable for transforming benzylic alcohols into aromatic aldehydes or ketones in organic synthesis.
• Fine chemical synthesis – widely used in pharmaceutical intermediates and specialty chemical manufacturing.
• Laboratory organic reactions – provides reliable oxidation performance in academic and R&D laboratories.
• Organic synthesis using MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols – enables selective oxidation reactions with minimal side products.
Problems This Product Solves
• Low oxidation conversion in laboratory synthesis → high-surface-area MnO₂ increases catalytic activity and reaction efficiency.
• Inconsistent oxidation yields between batches → controlled MnO₂ purity ensures reproducible results in repeated reactions.
• Excessive reagent consumption → active MnO₂ reduces required catalyst loading for many oxidation reactions.
• Side reactions and over-oxidation → selective surface chemistry improves reaction control.
• Difficult filtration after reaction → optimized particle structure allows easier solid-liquid separation.
Packaging & Supply
The product is typically supplied in 25 kg fiber drums with polyethylene liners to prevent moisture contamination. Export packaging is suitable for international transport and long-distance shipping. Laboratory samples (100 g–1 kg) are available for evaluation and reaction testing.
Customization & Technical Support
Manufacturers can provide particle size adjustment, purity optimization, and bulk supply according to process requirements. Technical support is available for reaction condition optimization and catalyst loading recommendations in oxidation processes.
FAQ
1. What purity level is typical for MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols?
Typical purity ranges from 85% to 92% MnO₂, depending on the production method. This purity level provides high catalytic activity while maintaining stable reaction performance in organic oxidation processes.
2. How should MnO₂ be stored to maintain activity?
MnO₂ powder should be stored in a dry, sealed container at room temperature. Avoid prolonged exposure to moisture or strong reducing agents to maintain its oxidation activity.
3. Is this MnO₂ suitable for pharmaceutical intermediate synthesis?
Yes. Activated MnO₂ is widely used in fine chemical and pharmaceutical intermediate synthesis due to its selectivity for allylic and benzylic oxidation reactions.
4. What catalyst loading is typically used in oxidation reactions?
Catalyst loading depends on the substrate and solvent system. In many laboratory reactions, MnO₂ is used in stoichiometric or slight excess relative to the alcohol substrate.
5. What is the shelf life of manganese dioxide powder?
Under proper dry storage conditions, MnO₂ typically maintains stable performance for 24 months or longer. Periodic testing is recommended for critical synthesis processes.
MnO₂ Powder for Oxidizing Allylic and Benzylic Alcohols

High-surface-area activated manganese dioxide (85–92% purity) specifically designed for selective oxidation in organic synthesis. Efficiently converts allylic and benzylic alcohols to corresponding aldehydes or ketones with minimal over-oxidation.
Product SKU: MnO2-ORG-OX
Product Brand: BTL New Material
Product In-Stock: InStock
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